Practice

Chemistry: Physical Chemistry: UPSC Previous Year Questions (Science and Technology)

15 previous year UPSC Prelims questions on physical chemistry are on this page, from 1996 to 2009. UPSC asks about the order of filling of orbitals, the magnetic quantum number, half-life, radioactive elements, the dry cell and glass that cuts ultraviolet rays. The explanations focus on the principle rather than on equations.

Explanations state facts as of the year each question was asked; words like “recently” refer to that year.

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UPSC 1999 Science and Technology · Chemistry: Physical Chemistry
Q11. Barium in a suitable form is administered to patients before an X-ray examination of the stomach, because:
UPSC 1999 Science and Technology · Chemistry: Physical Chemistry
Q12. Cobalt-60 is commonly used in radiation therapy because it emits:
UPSC 1998 Science and Technology · Chemistry: Physical Chemistry
Q13. Match the names of outstanding Indian scientists given in List I with area of their specialized work given in List II and select the correct answer by using the codes given below the lists:
List-IList-II
A. Dr. Raja Ramanna1. Plant chemistry
B. Dr. M.S. Swaminathan2. Nuclear physics
C. Prof. U.R Rao3. Thermodynamics & astrophysics
D. Prof. Meghnad Saha4. Space research
5. Agricultural science
UPSC 1998 Science and Technology · Chemistry: Physical Chemistry
Q14. Which one of the following elements is essential for the construction of nuclear reactors?
UPSC 1996 Science and Technology · Chemistry: Physical Chemistry
Q15. The alpha particle carries two positive charges. Its mass is very nearly equal to that of:

Answer key for these questions

QUPSC yearCorrect answer
111999(c) barium is a good absorber of X-rays and this helps the stomach to appear clearly in contrast with the other regions in the picture.
121999(c) Gamma rays
131998(c) A-2; B-5; C-4; D-3
141998(c) Zirconium
151996(b) an atom of helium

What UPSC has tested in Chemistry: Physical Chemistry

  • The order of filling of orbitals in an atom is governed by Aufbau’s principle.
  • The magnetic quantum number refers to the orientation of an orbital.
  • If a substance has a half-life of four months, three-fourths of it decays in eight months.
  • Crookes glass can cut off ultraviolet rays.
  • In a dry cell, ammonium chloride and zinc chloride are used as electrolytes.

Frequently asked questions

How many previous year UPSC questions are there on Chemistry: Physical Chemistry?

This page covers 15 previous year UPSC Prelims GS Paper-I questions on Chemistry: Physical Chemistry (Science and Technology), asked from 1996 to 2009. Each has the correct answer and an explanation.

What does Aufbau’s principle say?

Electrons fill the lowest-energy orbitals first before moving to higher ones. It governs the order in which orbitals are filled in an atom and so explains the arrangement of electrons.

How much of a substance is left after two half-lives?

One-fourth. After one half-life, half remains; after the second, half of that remains. With a half-life of four months, three-fourths of the substance has therefore decayed in eight months.